| The pyrolysis of isoxazole revisited: A new primary product and the pivotal role of the vinylnitrene. A low-temperature matrix isolation and computational study CM Nunes, I Reva, TMVD Pinho e Melo, R Fausto, T Solomek, T Bally Journal of the American Chemical Society 133 (46), 18911-18923, 2011 | 76 | 2011 |
| Conformational Switching in Pyruvic Acid Isolated in Ar and N2 Matrixes: Spectroscopic Analysis, Anharmonic Simulation, and Tunneling I Reva, CM Nunes, M Biczysko, R Fausto The Journal of Physical Chemistry A 119 (11), 2614-2627, 2015 | 71 | 2015 |
| Capture of an elusive nitrile ylide as an Intermediate in isoxazole–oxazole photoisomerization CM Nunes, I Reva, R Fausto The Journal of Organic Chemistry 78 (21), 10657-10665, 2013 | 66 | 2013 |
| Near-IR laser generation of a high-energy conformer of L-alanine and the mechanism of its decay in a low-temperature nitrogen matrix CM Nunes, L Lapinski, R Fausto, I Reva The Journal of Chemical Physics 138 (12), 2013 | 59 | 2013 |
| 1, 3-Dipolar cycloaddition of azomethine ylides generated from aziridines in supercritical carbon dioxide PJS Gomes, CM Nunes, AACC Pais, TMVDP e Melo, LG Arnaut Tetrahedron letters 47 (31), 5475-5479, 2006 | 58 | 2006 |
| Competitive nitrogen versus carbon tunneling CM Nunes, AK Eckhardt, I Reva, R Fausto, PR Schreiner Journal of the American Chemical Society 141 (36), 14340-14348, 2019 | 52 | 2019 |
| UV-laser photochemistry of isoxazole isolated in a low-temperature matrix CM Nunes, I Reva, TMVD Pinho e Melo, R Fausto The Journal of Organic Chemistry 77 (19), 8723-8732, 2012 | 52 | 2012 |
| Evidence of a nitrene tunneling reaction: spontaneous rearrangement of 2-formyl phenylnitrene to an imino ketene in low-temperature matrixes CM Nunes, SN Knezz, I Reva, R Fausto, RJ McMahon Journal of the American Chemical Society 138 (47), 15287-15290, 2016 | 51 | 2016 |
| Photochemistry of 2-formylphenylnitrene: A doorway to heavy-atom tunneling of a benzazirine to a cyclic ketenimine CM Nunes, I Reva, S Kozuch, RJ McMahon, R Fausto Journal of the American Chemical Society 139 (48), 17649-17659, 2017 | 49 | 2017 |
| Bond-shift isomers: the co-existence of allenic and propargylic phenylnitrile imines CM Nunes, I Reva, R Fausto, D Bégué, C Wentrup Chemical communications 51 (79), 14712-14715, 2015 | 40 | 2015 |
| Metal-Catalyzed Isomerization of 5-Heteroatom-Substituted Isoxazoles as a New Route to 2-Halo-2H-azirines NV Rostovskii, AV Agafonova, IA Smetanin, MS Novikov, AF Khlebnikov, ... Synthesis 49 (19), 4478-4488, 2017 | 34 | 2017 |
| Effects of entangled IR radiation and tunneling on the conformational interconversion of 2-cyanophenol AJ Lopes Jesus, CM Nunes, I Reva, SMV Pinto, R Fausto The Journal of Physical Chemistry A 123 (20), 4396-4405, 2019 | 31 | 2019 |
| Generation and Characterization of a 4π-Electron Three-Membered Ring 1H-Diazirine: An Elusive Intermediate in Nitrile Imine–Carbodiimide Isomerization CM Nunes, C Araujo-Andrade, R Fausto, I Reva The Journal of Organic Chemistry 79 (8), 3641-3646, 2014 | 29 | 2014 |
| 4-Isoxazolines and pyrroles from allenoates SMM Lopes, CM Nunes, TMVDP e Melo Tetrahedron 66 (32), 6078-6084, 2010 | 29 | 2010 |
| Cycloaddition of trifluoromethyl azafulvenium methides: synthesis of new trifluoromethylpyrrole-annulated derivatives CM Nunes, MR Silva, AM Beja, R Fausto, TMVDP e Melo Tetrahedron Letters 51 (2), 411-414, 2010 | 29 | 2010 |
| Chemistry of diazafulvenium methides in the synthesis of functionalized pyrazoles TMVD Pinho e Melo, CM Nunes, MIL Soares, JA Paixao, A Matos Beja, ... The Journal of Organic Chemistry 72 (12), 4406-4415, 2007 | 28 | 2007 |
| Thiazolo[3,4-b]indazole-2,2-dioxides as Masked Extended Dipoles: Pericyclic Reactions of Benzodiazafulvenium Methides MIL Soares, CM Nunes, CSB Gomes, TMVD Pinho e Melo The Journal of Organic Chemistry 78 (2), 628-637, 2013 | 27 | 2013 |
| Heavy‐Atom Tunneling Through Crossing Potential Energy Surfaces: Cyclization of a Triplet 2‐Formylarylnitrene to a Singlet 2, 1‐Benzisoxazole CM Nunes, LP Viegas, SA Wood, JPL Roque, RJ McMahon, R Fausto Angewandte Chemie International Edition 59 (40), 17622-17627, 2020 | 24 | 2020 |
| Kinetically unstable 2–isocyanophenol isolated in cryogenic matrices: Vibrational excitation, conformational changes and spontaneous tunneling AJL Jesus, I Reva, CM Nunes, JPL Roque, SMV Pinto, R Fausto Chemical Physics Letters 747, 137069, 2020 | 23 | 2020 |
| S–H rotamerization via tunneling in a thiol form of thioacetamide S Góbi, CM Nunes, I Reva, G Tarczay, R Fausto Physical Chemistry Chemical Physics 21 (31), 17063-17071, 2019 | 23 | 2019 |
