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David Kaphan
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A supramolecular microenvironment strategy for transition metal catalysis
DM Kaphan, MD Levin, RG Bergman, KN Raymond, FD Toste
Science 350 (6265), 1235-1238, 2015
3872015
Catalytic applications of vanadium: a mechanistic perspective
RR Langeslay, DM Kaphan, CL Marshall, PC Stair, AP Sattelberger, ...
Chemical reviews 119 (4), 2128-2191, 2018
3772018
Enabling new modes of reactivity via constrictive binding in a supramolecular-assembly-catalyzed aza-Prins cyclization
DM Kaphan, FD Toste, RG Bergman, KN Raymond
Journal of the American Chemical Society 137 (29), 9202-9205, 2015
1222015
Conformational selection as the mechanism of guest binding in a flexible supramolecular host
CM Hong, DM Kaphan, RG Bergman, KN Raymond, FD Toste
Journal of the American Chemical Society 139 (23), 8013-8021, 2017
942017
Nontraditional catalyst supports in surface organometallic chemistry
RJ Witzke, A Chapovetsky, MP Conley, DM Kaphan, M Delferro
ACS Catalysis 10 (20), 11822-11840, 2020
882020
Scope and mechanism of cooperativity at the intersection of organometallic and supramolecular catalysis
MD Levin, DM Kaphan, CM Hong, RG Bergman, KN Raymond, FD Toste
Journal of the American Chemical Society 138 (30), 9682-9693, 2016
882016
Metal–organic framework nodes as a supporting platform for tailoring the activity of metal catalysts
ZH Syed, F Sha, X Zhang, DM Kaphan, M Delferro, OK Farha
Acs Catalysis 10 (19), 11556-11566, 2020
592020
Electrophilic Organoiridium (III) Pincer Complexes on Sulfated Zirconia for Hydrocarbon Activation and Functionalization
ZH Syed, DM Kaphan, FA Perras, M Pruski, MS Ferrandon, EC Wegener, ...
Journal of the American Chemical Society 141 (15), 6325-6337, 2019
462019
Evidence for redox mechanisms in organometallic chemisorption and reactivity on sulfated metal oxides
RC Klet, DM Kaphan, C Liu, C Yang, AJ Kropf, FA Perras, M Pruski, ...
Journal of the American Chemical Society 140 (20), 6308-6316, 2018
402018
Surface Organometallic Chemistry of Supported Iridium (III) as a Probe for Organotransition Metal–Support Interactions in C–H Activation
DM Kaphan, RC Klet, FA Perras, M Pruski, C Yang, AJ Kropf, M Delferro
ACS Catalysis 8 (6), 5363-5373, 2018
372018
Functionalized NU-1000 with an Iridium Organometallic Fragment: SO2 Capture Enhancement
S Gorla, ML Díaz-Ramírez, NS Abeynayake, DM Kaphan, DR Williams, ...
ACS Applied Materials & Interfaces 12 (37), 41758-41764, 2020
242020
Mechanistic insights into C–H borylation of arenes with organoiridium catalysts embedded in a microporous metal–organic framework
ZH Syed, Z Chen, KB Idrees, TA Goetjen, EC Wegener, X Zhang, ...
Organometallics 39 (7), 1123-1133, 2020
242020
Computational investigation of the role of active site heterogeneity for a supported organovanadium (iii) hydrogenation catalyst
P Patel, RH Wells, DM Kaphan, M Delferro, RT Skodje, C Liu
ACS Catalysis 11 (12), 7257-7269, 2021
202021
Mechanistic Aspects of a Surface Organovanadium(III) Catalyst for Hydrocarbon Hydrogenation and Dehydrogenation
DM Kaphan, MS Ferrandon, RR Langeslay, G Celik, EC Wegener, C Liu, ...
ACS Catalysis 9, 11055-11066, 2019
162019
Development of activity–descriptor relationships for supported metal ion hydrogenation catalysts on silica
C Liu, J Camacho-Bunquin, M Ferrandon, A Savara, H Sohn, D Yang, ...
Polyhedron 152, 73-83, 2018
152018
Surface immobilized copper (I) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion
MS Eberhart, BT Phelan, J Niklas, EA Sprague-Klein, DM Kaphan, ...
Chemical Communications 56 (81), 12130-12133, 2020
142020
Revealing the Configuration and Conformation of Surface Organometallic Catalysts with DNP-Enhanced NMR
FA Perras, AL Paterson, ZH Syed, AJ Kropf, DM Kaphan, M Delferro, ...
The Journal of Physical Chemistry C 125 (24), 13433-13442, 2021
132021
Sulfated Zirconium Metal–Organic Frameworks as Well-Defined Supports for Enhancing Organometallic Catalysis
ZH Syed, MR Mian, R Patel, H Xie, Z Pengmei, Z Chen, FA Son, ...
Journal of the American Chemical Society 144 (37), 16883-16897, 2022
102022
Integrated Experimental and Computational K-Edge X-ray Absorption Near-Edge Structure Analysis of Vanadium Catalysts
P Patel, Z Lu, MG Jafari, C Hernández-Prieto, P Zatsepin, DJ Mindiola, ...
The Journal of Physical Chemistry C 126 (29), 11949-11962, 2022
102022
Activation of Low-Valent, Multiply M–M Bonded Group VI Dimers toward Catalytic Olefin Metathesis via Surface Organometallic Chemistry
Organometallics, 2020
102020
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