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David Kaphan
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A supramolecular microenvironment strategy for transition metal catalysis
DM Kaphan, MD Levin, RG Bergman, KN Raymond, FD Toste
Science 350 (6265), 1235-1238, 2015
3032015
Catalytic applications of vanadium: a mechanistic perspective
RR Langeslay, DM Kaphan, CL Marshall, PC Stair, AP Sattelberger, ...
Chemical reviews 119 (4), 2128-2191, 2018
2392018
Enabling new modes of reactivity via constrictive binding in a supramolecular-assembly-catalyzed aza-Prins cyclization
DM Kaphan, FD Toste, RG Bergman, KN Raymond
Journal of the American Chemical Society 137 (29), 9202-9205, 2015
992015
Scope and mechanism of cooperativity at the intersection of organometallic and supramolecular catalysis
MD Levin, DM Kaphan, CM Hong, RG Bergman, KN Raymond, FD Toste
Journal of the American Chemical Society 138 (30), 9682-9693, 2016
812016
Conformational selection as the mechanism of guest binding in a flexible supramolecular host
CM Hong, DM Kaphan, RG Bergman, KN Raymond, FD Toste
Journal of the American Chemical Society 139 (23), 8013-8021, 2017
782017
Metal–organic framework nodes as a supporting platform for tailoring the activity of metal catalysts
ZH Syed, F Sha, X Zhang, DM Kaphan, M Delferro, OK Farha
ACS Catalysis 10 (19), 11556-11566, 2020
382020
Nontraditional catalyst supports in surface organometallic chemistry
RJ Witzke, A Chapovetsky, MP Conley, DM Kaphan, M Delferro
ACS Catalysis 10 (20), 11822-11840, 2020
352020
Electrophilic organoiridium (III) pincer complexes on sulfated zirconia for hydrocarbon activation and functionalization
ZH Syed, DM Kaphan, FA Perras, M Pruski, MS Ferrandon, EC Wegener, ...
Journal of the American Chemical Society 141 (15), 6325-6337, 2019
262019
Surface Organometallic Chemistry of Supported Iridium (III) as a Probe for Organotransition Metal–Support Interactions in C–H Activation
DM Kaphan, RC Klet, FA Perras, M Pruski, C Yang, AJ Kropf, M Delferro
ACS Catalysis 8 (6), 5363-5373, 2018
262018
Evidence for redox mechanisms in organometallic chemisorption and reactivity on sulfated metal oxides
RC Klet, DM Kaphan, C Liu, C Yang, AJ Kropf, FA Perras, M Pruski, ...
Journal of the American Chemical Society 140 (20), 6308-6316, 2018
262018
Functionalized NU-1000 with an Iridium Organometallic Fragment: SO2 Capture Enhancement
S Gorla, ML Díaz-Ramírez, NS Abeynayake, DM Kaphan, DR Williams, ...
ACS Applied Materials & Interfaces 12 (37), 41758-41764, 2020
172020
Mechanistic insights into C–H borylation of arenes with organoiridium catalysts embedded in a microporous metal–organic framework
ZH Syed, Z Chen, KB Idrees, TA Goetjen, EC Wegener, X Zhang, ...
Organometallics 39 (7), 1123-1133, 2020
142020
Development of activity–descriptor relationships for supported metal ion hydrogenation catalysts on silica
C Liu, J Camacho-Bunquin, M Ferrandon, A Savara, H Sohn, D Yang, ...
Polyhedron 152, 73-83, 2018
112018
Mechanistic Aspects of a Surface Organovanadium(III) Catalyst for Hydrocarbon Hydrogenation and Dehydrogenation
DM Kaphan, MS Ferrandon, RR Langeslay, G Celik, EC Wegener, C Liu, ...
ACS Catalysis 9, 11055-11066, 2019
92019
Computational Investigation of the Role of Active Site Heterogeneity for a Supported Organovanadium (III) Hydrogenation Catalyst
P Patel, RH Wells, DM Kaphan, M Delferro, RT Skodje, C Liu
ACS Catalysis 11 (12), 7257-7269, 2021
82021
Activation of Low-Valent, Multiply M–M Bonded Group VI Dimers toward Catalytic Olefin Metathesis via Surface Organometallic Chemistry
Organometallics, 2020
72020
Revealing the Configuration and Conformation of Surface Organometallic Catalysts with DNP-Enhanced NMR
FA Perras, AL Paterson, ZH Syed, AJ Kropf, DM Kaphan, M Delferro, ...
The Journal of Physical Chemistry C 125 (24), 13433-13442, 2021
62021
Surface immobilized copper (i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion
MS Eberhart, BT Phelan, J Niklas, EA Sprague-Klein, DM Kaphan, ...
Chemical Communications 56 (81), 12130-12133, 2020
42020
Photocatalytic Transfer Hydrogenation in Water: Insight into Mechanism and Catalyst Speciation
DM Kaphan, KR Brereton, RC Klet, RJ Witzke, AJM Miller, KL Mulfort, ...
Organometallics 40 (10), 1482-1491, 2021
32021
Phosphorus‐Atom Transfer from Phosphaethynolate to an Alkylidyne
MG Jafari, Y Park, B Pudasaini, T Kurogi, PJ Carroll, DM Kaphan, J Kropf, ...
Angewandte Chemie 133 (46), 24616-24622, 2021
22021
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Articles 1–20